S4.11.1 Chapter 1
Unstable nuclei
Carbon 12 stays the same for ever, but carbon 14 does not. What is different about them?
Your guess
Pick one before you read on. It is fine to be wrong.
By the end you can
- Explain why some isotopes are unstable and decay
- Explain that decay is random and cannot be predicted for one atom
Most atoms stay as they are for ever. A few do not. They change by themselves, and this book is about those few. They matter because of what they give out, and because we can use it and must respect it.
Remember the atom. At its centre is a tiny nucleus of protons and neutrons. Protons have a positive charge and neutrons have none. The electrons are outside it. The mass number is the number of protons plus neutrons.
Protons push each other apart, because like charges repel. Something stronger must hold the nucleus together. It is called the strong nuclear force. It pulls protons and neutrons together, but only over a very short distance.
Neutrons help. They add to the pull and add no push. A nucleus holds together when it has the right mix of protons and neutrons. We call that nucleus stable: it stays as it is for ever.
A nucleus is unstable when the mix is wrong. It may have too many neutrons, or too few, for its protons. Or it may be very large, like uranium. An unstable nucleus can change.
We call an unstable nucleus radioactive. When it changes, we say it decays. It gives out radiation, which is energy or fast particles from the nucleus. The nucleus turns into a new, more stable one, sometimes of another element.
Worked example
A nucleus of carbon 14 has 6 protons and mass number 14. How many neutrons does it have?
- Mass number = protons + neutrons.
- neutrons = mass number − protons.
- neutrons = 14 − 6 = 8.
Answer: 8 neutrons
Try it
Draw a nucleus
You need: paper, a pencil.
- Draw 5 small circles and put a plus sign in each. These are protons.
- Draw 6 plain circles beside them. These are neutrons.
- Count all 11 circles. This number is the mass number.
- Write the name of the element: 5 protons make boron. Then write boron 11.
- Now draw the nucleus of boron 10 in the same way. How many neutrons does it have?
What you will see: You can draw any mix of circles you like. Nature does not. Only some mixes hold together, and the rest are unstable. Boron 11 and boron 10 are both stable, but a boron nucleus with many more neutrons is not.
Now a puzzle. Think of a large sample of one unstable kind of nucleus. All the nuclei are identical. Yet they do not all decay together. One decays now, and its neighbour waits for years. Why?
The answer is that decay is random. Nothing makes a nucleus decay at a certain time. Each nucleus has a certain chance of decaying in each second. This chance is the same for every nucleus of that kind. We cannot say when it will happen to one of them.
Random does not mean that nothing can be said. A coin is random when tossed once. Yet 1 000 tosses give about 500 heads. In the same way, we cannot predict one nucleus, but a huge number of them behave in a steady, predictable way. The next chapters use this.
Worked example
A counter gave these counts in five periods of 10 s from one source: 31, 27, 35, 29, 33. What was the mean count in 10 s?
- mean = total ÷ number of readings.
- total = 31 + 27 + 35 + 29 + 33 = 155.
- mean = 155 ÷ 5 = 31 counts.
Answer: 31 counts
One more fact. Heating a sample does not change how likely its nuclei are to decay. Nor does cooling it, squeezing it, or joining its atoms into a compound. The cause is inside the nucleus, and ordinary changes outside it do not reach there. A very small effect has been measured for a few rare kinds of decay. It does not matter here.
A wrong idea many people have
A substance is radioactive because it has been heated or charged with energy. It will calm down if it is cooled.
Why it feels right: A hot stove glows and gives out heat, and it stops when it cools. It seems radiation works the same way.
The test that breaks it: A radioactive sample kept in a very cold place still decays at the same rate. So does the same sample heated. Neither changes the nucleus.
What is true: Radiation comes from the nucleus. It happens because the nucleus is unstable. Heat, cold and chemistry do not switch it on or off.
A wrong idea many people have
Each unstable nucleus has its own timer, so it decays at a fixed time that we could work out.
Why it feels right: A big sample decays in a steady way, so each nucleus seems to follow a plan.
The test that breaks it: Scientists count the decays from one source several times, for the same length of time. The counts differ each time, as in the bar chart. A plan would give the same count.
What is true: Each decay is random. We can give the chance, and for a huge number of nuclei the total is steady. We cannot say which nucleus goes next.
Key words
- nucleus
- the tiny centre of an atom, made of protons and neutrons.
- stable
- a nucleus that stays as it is for ever.
- unstable
- a nucleus that may change by itself.
- radioactive
- having unstable nuclei that decay and give out radiation.
- decay
- the change of an unstable nucleus into a more stable one.
- radiation
- energy or fast particles given out by an unstable nucleus.
- random
- not possible to predict for one nucleus, only as a chance.
Back to your guess
The answer is A: Carbon 14 has two more neutrons in its nucleus.
Both are carbon, so both have 6 protons and 6 electrons. Carbon 14 has 8 neutrons and carbon 12 has 6. That mix makes the nucleus of carbon 14 unstable.
Check yourself
Try each one before you look. A wrong answer tells you where to go next.
Which statement about an unstable nucleus is true?
See the answer
It may change by giving out radiation.
An unstable nucleus can decay. When it does, it gives out radiation and becomes a new, more stable nucleus.
- If you chose A: That describes a stable nucleus. An unstable nucleus may change.
- If you chose B: Neutrons are not the problem. Carbon 14 is unstable and has 8 of them. It is the mix of protons and neutrons that matters.
- If you chose D: Electrons are outside the nucleus. The instability is inside the nucleus, and electrons do not cause it. Go to S4.6.1.
Carbon 12 and carbon 14 both have 6 protons. Why is only carbon 14 unstable?
See the answer
Its nucleus has too many neutrons for its protons.
Carbon 14 has 8 neutrons for 6 protons. This mix is not stable, so the nucleus can decay. Carbon 12 has 6 and 6, which is stable.
- If you chose B: Both have 6 electrons, and the electrons are not in the nucleus. The cause is in the nucleus. Go to S4.6.3.
- If you chose C: Both have 6 protons. That is why both are carbon. Only the neutrons differ. Go to S4.6.3.
- If you chose D: Many heavy nuclei, such as lead 206, are stable. A large mass number alone does not make a nucleus unstable.
A scientist wants a radioactive sample to decay faster. Which of these changes how fast its nuclei decay?
See the answer
None of these. They do not change it.
Decay happens inside the nucleus. Heat, pressure and chemical changes happen outside it, so they do not change how likely a nucleus is to decay.
- If you chose A: Heat acts on the atoms from outside. It does not reach the nucleus, so it does not change the decay.
- If you chose B: Pressure does not reach the nucleus either. The decay is the same.
- If you chose C: A chemical change moves electrons. It leaves the nucleus alone, so the decay is the same. Go to S3.6.1.
A sample holds a million identical unstable nuclei. Which statement is true?
See the answer
No one can tell which nucleus will decay next.
Decay is random. We can give the chance for each nucleus, and the total for a huge number is steady. We cannot say which nucleus goes next.
- If you chose A: There is no fixed order. Each nucleus has only a chance of decaying, and the chance is the same for all.
- If you chose C: They do not. The decays are spread out over time, at random.
- If you chose D: Position does not matter. Every nucleus of the kind has the same chance at any moment.
A counter reads 44, 38, 47, 41 and 45 counts in five periods of 10 s from one source. Bars 1 to 5 in the picture are the five counts. What do the different readings show?
See the answer
Decay is random, so the count changes from one period to the next.
The number of decays in a short time varies by chance. The readings stay close to a steady mean but are not equal.
- If you chose A: The counts go up and down, not steadily up. A source does not get stronger as it decays.
- If you chose B: A working counter gives different readings too, because decay is random. A broken counter would be far off, or stuck.
- If you chose C: That may be true, but it does not explain readings that differ. Even a pure source shows this.
A nucleus of uranium 238 has 92 protons. How many neutrons does it have?
See the answer
146
neutrons = mass number − protons = 238 − 92 = 146.
How many neutrons does the nucleus in the picture have?
See the answer
4 neutrons
The plain circles are neutrons. Count the circles that have no plus sign: there are 4.
A nucleus of cobalt 60 has 27 protons. How many neutrons does it have?
See the answer
33 neutrons
neutrons = mass number − protons = 60 − 27 = 33.
A counter gave 52, 48, 55 and 49 counts in four periods of 10 s from one source. What was the mean count in 10 s?
See the answer
51 counts
total = 52 + 48 + 55 + 49 = 204. mean = 204 ÷ 4 = 51.
Keep it
Copy this into your exercise book.
A nucleus is stable or unstable. An unstable one decays and gives out radiation. The wrong mix of neutrons and protons, or a very large nucleus, can cause it. Decay is random. Heat does not change it.
Draw: Carbon 12 and carbon 14 side by side as circles: 6 protons and 6 neutrons, then 6 protons and 8 neutrons.